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Trailing following a contentious 2-1 defeat in Bilbao last week, Barca had to wait for their breakthrough before it arrived in landmark fashion 10 minutes from half-time.
Luis Suarez volleyed his 100th goal for the club on the end of a move that fittingly featured Messi and Neymar – it was the 300th goal for MSN since the awesome forward trio began playing together in 2014.
Neymar won and converted a penalty early in the second period, but Athletic hit back through wideman Enric Saborit, a Barcelona-born product of the Espanyol youth system.